Shopping Cart

No products in the cart.

ASTM-D5128:2014 Edition(Redline)

$41.17

D5128-14 Standard Test Method for On-Line pH Measurement of Water of Low Conductivity (Redline)

Published By Publication Date Number of Pages
ASTM 2014 16
Guaranteed Safe Checkout
Categories: ,

If you have any questions, feel free to reach out to our online customer service team by clicking on the bottom right corner. We’re here to assist you 24/7.
Email:[email protected]

ASTM D5128-14

Redline Standard: Standard Test Method for On-Line pH Measurement of Water of Low Conductivity

ASTM D5128

Scope

1.1 This test method covers the precise on-line determination of pH in water samples of conductivity lower than 100 μS/cm (see Table 1 and Table 2) over the pH range of 3 to 11 (see Fig. 1), under field operating conditions. pH measurements of water of low conductivity are problematic for conventional pH electrodes, methods, and related measurement apparatus.

TABLE 1 Calculated Conductivity and pH Values at 25°C of Low Concentrations of NaOH in Pure Water A
Note 1This table tabulates the theoretical conductivity and pH values of low levels of NaOH in pure water as calculated from available thermodynamic data.
Note 2To illustrate the high sensitivity of the sample pH at these low concentrations to contaminants, the last column lists errors that would result if the sample were contaminated with an additional 1 mg/L through sample or equipment handling errors.
A Data courtesy of Ref (1).B This data developed from algorithms originally published in Ref (2).
B The boldface numbers in parentheses refer to a list of references at the end of this standard.

TABLE 2 Calculated Conductivity and pH Values at 25°C of Low Concentrations of HCl in Pure Water A
Note 1This table tabulates the theoretical conductivity and pH values of low levels of HCl in pure water as calculated from available thermodynamic data
Note 2To illustrate the high sensitivity of the sample pH at these low concentrations to contaminants, the last column lists errors that would result if the sample were contaminated with an additional 1 mg/L through sample or equipment handling errors.
A Data courtesy of Ref (1). This data developed from algorithms originally published in Ref (2).

FIG. 1 Restrictions Imposed by the Conductivity pH Relationship

1.2 This test method includes the procedures and equipment required for the continuous pH measurement of low conductivity water sample streams including the requirements for the control of sample stream pressure, flow rate, and temperature. For off-line pH measurements in low conductivity samples, refer to Test Method D5464.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Keywords

high purity; low conductivity; on-line; pH; calculated pH

ICS Code

ICS Number Code 71.040.50 (Physicochemical methods of analysis)

DOI: 10.1520/D5128-14

ASTM-D5128
$41.17