{"id":465119,"date":"2024-10-20T10:38:49","date_gmt":"2024-10-20T10:38:49","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bsi-pd-cen-ts-180442024\/"},"modified":"2024-10-26T19:38:55","modified_gmt":"2024-10-26T19:38:55","slug":"bsi-pd-cen-ts-180442024","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bsi-pd-cen-ts-180442024\/","title":{"rendered":"BSI PD CEN\/TS 18044:2024"},"content":{"rendered":"
This document specifies a chromatographic method for the determination of levoglucosan in aqueous or organic extracts of filter samples collected in accordance with EN 12341:2023 [5]. The method has been tested for concentrations of ca. 10 ng\/m3 up to ca. 3 000 ng\/m3 with a sampling duration of 24 h. The procedure is also suitable for the determination of galactosan and mannosan. Depending on the analysis instrumentation used, the carbohydrates inositol, glycerol, threitol\/erythritol, xylitol, arabitol, sorbitol, mannitol, threalose, mannose, glucose, galactose and fructose can also be determined. However, no performance characteristics are given for these compounds in this document.<\/p>\n
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2<\/td>\n | undefined <\/td>\n<\/tr>\n | ||||||
8<\/td>\n | 1 Scope 2 Normative references 3 Terms and definitions 4 Symbols and abbreviations <\/td>\n<\/tr>\n | ||||||
9<\/td>\n | 5 Principle 6 Equipment 6.1 Sampling 6.1.1 Sampling device 6.1.2 Particle filter 6.2 Apparatus for sample preparation 6.3 Analytical equipment 6.3.1 IC-PAD <\/td>\n<\/tr>\n | ||||||
10<\/td>\n | 6.3.2 GC-MS 6.4 Chemicals and accessories <\/td>\n<\/tr>\n | ||||||
11<\/td>\n | 7 Sampling 8 Sample preparation and analysis 8.1 General 8.2 IC-PAD method 8.2.1 Sample preparation 8.2.2 Eluent preparation 8.2.3 Analysis 8.2.4 Calibration <\/td>\n<\/tr>\n | ||||||
12<\/td>\n | 8.3 GC-MS method 8.3.1 Sample preparation 8.3.2 Analysis 8.3.3 Calibration 9 Calculation of results <\/td>\n<\/tr>\n | ||||||
13<\/td>\n | 10 Measurement uncertainty 10.1 General 10.2 Evaluation according to ISO 57252 <\/td>\n<\/tr>\n | ||||||
14<\/td>\n | 10.3 Evaluation of laboratory data according to ISO\/IEC Guide 98-3 <\/td>\n<\/tr>\n | ||||||
15<\/td>\n | 11 Limit of detection and limit of quantification <\/td>\n<\/tr>\n | ||||||
16<\/td>\n | 12 Interferences 12.1 General 12.2 IC-PAD <\/td>\n<\/tr>\n | ||||||
17<\/td>\n | 12.3 GC-MS 13 Quality assurance and quality control <\/td>\n<\/tr>\n | ||||||
18<\/td>\n | Annex A (informative)Application examples of the IC-PAD method A.1 Example 1 A.1.1 Apparatus A.1.2 Operating parameters <\/td>\n<\/tr>\n | ||||||
19<\/td>\n | A.1.3 Chemicals and accessories <\/td>\n<\/tr>\n | ||||||
20<\/td>\n | A.1.4 Procedure A.1.4.1 Calibration standards A.1.4.2 Eluent preparation A.1.4.3 Sample preparation <\/td>\n<\/tr>\n | ||||||
21<\/td>\n | A.1.4.4 Preparation of instrumentation A.1.4.5 Analysis A.1.4.6 Limits of detection <\/td>\n<\/tr>\n | ||||||
22<\/td>\n | A.1.4.7 Chromatograms <\/td>\n<\/tr>\n | ||||||
23<\/td>\n | A.2 Example 2 A.2.1 Apparatus <\/td>\n<\/tr>\n | ||||||
24<\/td>\n | A.2.2 Operating parameters A.2.3 Chemicals and accessories <\/td>\n<\/tr>\n | ||||||
25<\/td>\n | A.2.4 Procedure A.2.4.1 Calibration standards A.2.4.2 Eluent preparation A.2.4.3 Sample preparation <\/td>\n<\/tr>\n | ||||||
26<\/td>\n | A.2.4.4 Preparation of instrumentation A.2.4.5 Separation and detection conditions <\/td>\n<\/tr>\n | ||||||
27<\/td>\n | A.2.4.6 Analysis A.2.4.7 Analysis validation A.2.4.8 Limits of detection <\/td>\n<\/tr>\n | ||||||
28<\/td>\n | A.2.4.9 Chromatograms <\/td>\n<\/tr>\n | ||||||
30<\/td>\n | Annex B (informative)Application example of the GC-MS method B.1 Apparatus B.2 GC\/MS operating parameters B.3 Chemicals <\/td>\n<\/tr>\n | ||||||
31<\/td>\n | B.4 Procedure B.4.1 Calibration standards <\/td>\n<\/tr>\n | ||||||
32<\/td>\n | B.4.2 Sample preparation B.4.2.1 Spiking the samples with surrogate standard B.4.2.2 Ultrasonic extraction B.4.2.3 Derivatisation B.4.2.4 Analysis <\/td>\n<\/tr>\n | ||||||
34<\/td>\n | Annex C (informative)Calculation of the measurement uncertainty using results of a laboratory intercomparison C.1 General C.2 Calculations according to ISO 57252 <\/td>\n<\/tr>\n | ||||||
35<\/td>\n | C.3 Calculation of uncertainty parameters according to ISO 13528 (Q\/Hampel method) <\/td>\n<\/tr>\n | ||||||
36<\/td>\n | C.4 Comparison of the two calculation methods <\/td>\n<\/tr>\n | ||||||
39<\/td>\n | Annex D (informative)Possible requirements for the uncertainty of single steps in work up and analysis for an overall uncertainty of 40 % <\/td>\n<\/tr>\n | ||||||
41<\/td>\n | Annex E (informative)Calculation of the limit of detection from the calibration function <\/td>\n<\/tr>\n | ||||||
42<\/td>\n | Annex F (informative)Illustrative chromatograms <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":" Ambient air. Determination of the concentration of levoglucosan. Chromatographic method<\/b><\/p>\n |